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Comprehensive performance analysis and optimization of 1,3-dimethylimidazolylium dimethylphosphate-water

Gorakshnath TAKALKAR, Ahmad K. SLEITI

《能源前沿（英文）》 2022年 第16卷 第3期   页码 521-535 doi: 10.1007/s11708-021-0720-9

摘要： The energy and exergy analyses of the absorption refrigeration system (ARS) using H O-[mmim][DMP] mixture were investigated for a wide range of temperature. The equilibrium Dühring ( - - ) and enthalpy ( - - ) of mixture were assessed using the excess Gibbs free non-random two liquid (NRTL) model for a temperature range of 20°C to 140°C and from 0.1 to 0.9. The performance validation of the ARS cycle showed a better coefficient of performance (COP) of 0.834 for H O-[mmim][DMP] in comparison to NH -H O, H O-LiBr, H O-[emim][DMP], and H O-[emim][BF4]. Further, ARS performances with various operating temperatures of the absorber ( ), condenser ( ), generator ( ), and evaporator ( ) were simulated and optimized for a maximum COP and exergetic COP (ECOP). The effects of from 50°C to 150°C and and from 30°C to 50°C on COP and ECOP, the , , and circulation ratio (CR) of the ARS were evaluated and optimized for from 5°C to 15°C. The optimization revealed that needed to achieve a maximum COP which was more than that for a maximum ECOP. Therefore, this investigation provides criteria to select low grade heat source temperature. Most of the series flow of the cases of cooling water from the condenser to the absorber was found to be better than the absorber to the condenser.

关键词： ionic liquid driven absorption cycle     H2O-[mmim][DMP]     coefficient of performance (COP)     exergy analysis     thermodynamics mixture property    

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Performance of rolling piston type rotary compressor using fullerenes (C70) and NiFe

Ruixiang WANG,Yihao ZHANG,Yi LIAO

《能源前沿（英文）》 2020年 第14卷 第3期   页码 644-648 doi: 10.1007/s11708-017-0453-y

摘要： A novel way for a compressor to improve its coefficient of performance was proposed in this paper. Fullerenes (C70) and NiFe O nanocomposites were modified by span 80 and dispersed in refrigeration oil by solid grinding (SG). Besides, the tribological properties of the nanocomposites were investigated using a four ball friction tester. The results show that when the mass concentration of fullerenes nanocomposite is higher than 60 ppm and the concentration of nano-oil is 2 g/L, the friction coefficient decreases from 0.13 to 0.06 which means the wear is reduced. The coefficient of performance of the compressor under the air conditioning test condition can be raised by 1.23%.

关键词： rotary compressor     friction coefficient     nanocomposite materials     coefficient of performance     fullerenes (C70)    

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How diplomacy saved the COP21 Paris Climate Conference, but now, can we save ourselves?

D. Nathaniel MULCAHY, David L. MULCAHY

《能源前沿（英文）》 2018年 第12卷 第3期   页码 344-352 doi: 10.1007/s11708-017-0498-y

摘要：

To solve a problem, three things are necessary: awareness, means, and will. The 2015 COP21 Paris accord was a masterful, perhaps even world-saving, diplomatic advance toward making the world aware of climate change. Some of that success may have been because publications from the IPCC and the National Academy of Science were made available, on line, as prepublication offerings, in order to be widely viewed before the Paris Climate Conference. This provided diplomats and negotiators with the latest information about climate change, its nearness in time, its consequences, and how well current mitigation technologies can succeed. Whatever the reasons, the Paris Climate Conference, was a success. Leaders of 195 nations agreed that climate change is a real and present danger to life as is known to all. This important understanding was accomplished despite the presentation of well established scientific facts which, without very diplomatic handling, could easily have evoked overwhelming political opposition to an agreement and thus another COP failure. In this paper, the fact that how some scientific truths, written specifically to be overlooked, were presented in order to prepare COP21 participants for the conference is explained. Besides, the effectiveness and efficiency of currently favored mitigation policies, the extent of ongoing progress to better ones, and finally, how a new appreciation of climate change consequences can strengthen the will of nation states and industries to work toward solutions are evaluated.

关键词： COP21     Paris     climate     agreement     offsets     mitigation     IPCC    

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Nonlinear design-point performance adaptation approaches and their comparisons for gas turbine applications

Y. G. LI, P. PILIDIS,

《能源前沿（英文）》 2009年 第3卷 第4期   页码 446-455 doi: 10.1007/s11708-009-0042-9

摘要： Accurate performance simulation and understanding of gas turbine engines is very useful for gas turbine manufacturers and users alike and such a simulation normally starts from its design point. When some of the engine component parameters for an existing engine are not available, they must be estimated in order that the performance analysis can be started. Therefore, the simulated design point performance of an engine may be slightly different from its actual performance. In this paper, two nonlinear gas turbine design-point performance adaptation approaches have been presented to best estimate the unknown component parameters and match available design point engine performance, one using a nonlinear matrix inverse adaptation method and the other using a Genetic Algorithm-based adaptation approach. The advantages and disadvantages of the two adaptation methods have been compared with each other. In the approaches, the component parameters may be compressor pressure ratios and efficiencies, turbine entry temperature, turbine efficiencies, engine mass flow rate, cooling flows, and by-pass ratio, etc. The engine performance parameters may be thrust and SFC for aero engines, shaft power, and thermal efficiency for industrial engines, gas path pressures, temperatures, etc. To select the most appropriate to-be-adapted component parameters, a sensitivity bar chart is used to analyze the sensitivity of all potential component parameters against the engine performance parameters. The two adaptation approaches have been applied to a model gas turbine engine. The application shows that the sensitivity bar chart is very useful in the selection of the to-be-adapted component parameters, and both adaptation approaches are able to produce good quality engine models at design point. The comparison of the two adaptation methods shows that the nonlinear matrix inverse method is faster and more accurate, while the genetic algorithm-based adaptation method is more robust but slower. Theoretically, both adaptation methods can be extended to other gas turbine engine performance modelling applications.

关键词： gas turbine     engine     performance adaptation     performance matching     design-point performance simulation     influence coefficient matrix     genetic algorithm    

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>In situ growth of phosphorized ZIF-67-derived amorphous CoP/Cu2O@CF electrocatalyst

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1430-1439 doi: 10.1007/s11705-023-2320-1

摘要： Transition metal phosphides have been extensively studied for catalytic applications in water splitting. Herein, we report an in situ phosphorization of zeolitic imidazole frameworks (ZIF-67) to generate amorphous cobalt phosphide/ZIF-67 heterojunction on a self-supporting copper foam (CF) substrate with excellent performance for hydrogen evolution reaction (HER). The needle-leaf like copper hydroxide was anchored on CF surface, which acted as implantation to grow ZIF-67. The intermediate product was phosphorized to obtain final electrocatalyst (CoP/Cu2O@CF) with uniform particle size, exhibiting a rhombic dodecahedron structure with wrinkles on the surface. The electrochemical measurement proved that CoP/Cu2O@CF catalyst exhibited excellent HER activity and long-term stability in 1.0 mol·L–1 KOH solution. The overpotential was only 62 mV with the Tafel slope of 83 mV·dec–1 at a current density of 10 mA·cm–2, with a large electrochemical active surface area. It also showed competitive performance at large current which indicated the potential application to industrial water electrolysis to produce hydrogen. First-principle calculations illustrated that benefit from the construction of CoP/ZIF-67 heterojunction, the d-band center of CoP downshifted after bonding with ZIF-67 and the Gibbs free energy (ΔGH*) changed from –0.18 to –0.11 eV, confirming both decrease in overpotential and excellent HER activity. This work illustrates the efficient HER activity of CoP/Cu2O@CF catalyst, which will act as a potential candidate for precious metal electrocatalysts.

关键词： CoP/Cu2O@CF     electrocatalyst     phosphorization     HER     DFT    

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Evaluation of the performance of a centralized ground-water heat pump system in cold climate region

Shilei LU,Zhe CAI,Li ZHANG,Yiran LI

《能源前沿（英文）》 2014年 第8卷 第3期   页码 394-402 doi: 10.1007/s11708-014-0310-1

摘要： The aim of this study is to evaluate the performance of a centralized open-loop ground-water heat pump (GWHP) system for climate conditioning in Beijing with a cold climate in China. Thus, a long-time test was conducted on a running GWHP system for the heating season from December 2011 to March 2012. The analysis of the testing data indicates that the average heat-pump coefficient of performance (COP) and the COP of the system (COPs) are 4.27 and 2.59. The low value and large fluctuation in the range of COP are found to be caused by the heat transfixion in the aquifer and the bypass in the circulation loop. Therefore, some suggestions are proposed to improve the performance for GWHPs in the cold climate region in China.

关键词： ground-water heat pump (GWHP)     actual coefficient of performance     heat transfixion    

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建设项目协调管理绩效评价

郭峰,刘慧

《中国工程科学》 2011年 第13卷 第8期   页码 97-102

摘要：

文章将功能系数法与广泛应用于管理评价的逻辑框架法进行综合运用，认为项目及组织的可持续发展是建设项目协调管理的最高境界，从目标协调管理绩效、组织协调管理绩效、利益相关方协调管理绩效及项目和组织可持续发展性4个方面建立了建设项目协调管理绩效评价指标体系，并给出各指标的计算方法，运用功能系数法计算建设项目协调管理绩效综合评价功能系数，从而有效量化了对建设项目协调管理绩效的综合评价。最后，通过算例研究，验证了指标体系构建方法及各指标计算方法的可行性，这个方法可以有效地衡量协调管理的功能。

关键词： 建设项目协调管理     绩效评价指标体系     功能系数法    

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Experimental study on performance of passive and active solar stills in Indian coastal climatic condition

R. LALITHA NARAYANA, V. RAMACHANDRA RAJU

《能源前沿（英文）》 2020年 第14卷 第1期   页码 105-113 doi: 10.1007/s11708-018-0536-4

摘要： This present work is aimed to examine the effect of mass flow rate on distillate output and performance of a solar still in active mode. Outdoor experiments were conducted at the coastal town, Kakinada (16° 93′N/83° 33′E), Andhra Pradesh, India. A solar still with a 30° of fixed cover inclination, 1m of effective basin area, and a flat-plate collector (FPC) with an effective area of 2 m were used. An attempt was also made earlier in passive mode to optimize the water depth for the same solar still for maximum yield and distillation efficiency. For the passive still, it is observed that the capacity of heat storage and heat drop are significant parameters that affect the still performance. For the selected still design, the study reveals that 0.04 m water depth is the optimum value for specific climatic conditions. In the active solar still, with the optimum water depth, different flow rates of 0.5, 1 and 1.5 L/min are considered through FPC. It is observed that both the mass flow rate and the variation of internal heat transfer coefficients with the mass flow rate have a significant effect on the yield and performance of the still. The experimental results show that the combination of 1.5 L/min mass flow rate and an optimum water depth of 0.04m leads to a maximum yield for the active solar still. The enhanced yield of the active solar still is 57.55%, compared with that of the passive solar still, due to increase in area of radiation collection and more heat absorption rate.

关键词： distillation efficiency     solar still     heat transfer coefficient     water depth     optimum and mass flow rate    

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RETRACTED ARTICLE: Momentum exchange coefficient for two jet flows mixing in a tee junction

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 2161-2161 doi: 10.1007/s11705-009-0143-3

摘要： RETRACTED ARTICLE: Momentum exchange coefficient for two jet flows mixing in a tee junction

关键词： tee junction     Momentum exchange coefficient     RETRACTED    

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原子界面催化合成SnP/CoP异质纳米晶嵌入碳杂化物用于高功率型锂离子电池 Article

胡晨, 胡彦杰, 陈爱平, 段学志, 江浩, 李春忠

《工程（英文）》 2022年 第18卷 第11期   页码 154-160 doi: 10.1016/j.eng.2021.11.026

摘要： 因此，在还原氧化石墨烯（rGO）包裹的碳骨架内合成了SnP/CoP异质纳米晶。充放电机理分析表明尺寸为4.0 nm的SnP/CoP纳米晶具有高反应可逆性，且CoP在较高电位生成的金属Co加速了低电位SnP反应的动力学，从而赋予材料超快充放电能力。

关键词： 催化磷化     磷化锡     异质纳米晶     快速充电     锂离子电池    

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Experimental study of heat transfer coefficient with rectangular baffle fin of solar air heater

Foued CHABANE,Nesrine HATRAF,Noureddine MOUMMI

《能源前沿（英文）》 2014年 第8卷 第2期   页码 160-172 doi: 10.1007/s11708-014-0321-y

摘要： This paper presents an experimental analysis of a single pass solar air collector with, and without using baffle fin. The heat transfer coefficient between the absorber plate and air can be considerably increased by using artificial roughness on the bottom plate and under the absorber plate of a solar air heater duct. An experimental study has been conducted to investigate the effect of roughness and operating parameters on heat transfer. The investigation has covered the range of Reynolds number from 1259 to 2517 depending on types of the configuration of the solar collectors. Based on the experimental data, values of Nusselt number have been determined for different values of configurations and operating parameters. To determine the enhancement in heat transfer and increment in thermal efficiency, the values of Nusselt have been compared with those of smooth duct under similar flow conditions.

关键词： Nusselt number     flow rate     heat transfer     heat transfer coefficient     thermal efficiency     forced convection    

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A photolysis coefficient for characterizing the response of aqueous constituents to photolysis

David R. HOKANSON,Ke LI,R. Rhodes TRUSSELL

《环境科学与工程前沿（英文）》 2016年 第10卷 第3期   页码 428-437 doi: 10.1007/s11783-015-0780-3

摘要： UV photolysis and UV based advanced oxidation processes (AOPs) are gaining more and more attention for drinking water treatment. Quantum yield ( ) and molar absorption coefficient ( ) are the two critical parameters measuring the effectiveness of photolysis of a compound. The product of the two was proposed as a fundamental measure of a constituent’s amenability to transformation by photolysis. It was shown that this product, named the photolysis coefficient, , can be determined using standard bench tests and captures the properties that govern a constituent’s transformation when exposed to light. The development showed the photolysis coefficient to be equally useful for microbiological, inorganic and organic constituents. Values of calculated by the authors based on quantum yield and molar absorption coefficient data from the literature were summarized. Photolysis coefficients among microorganisms ranged from 8500 to more than 600000 and are far higher than for inorganic and organic compounds, which varied over a range of approximately 10 to 1000 and are much less sensitive to UV photolysis than the microorganisms.

关键词： UV photolysis     disinfection     advanced oxidation     N-nitrosodimethylamine     quantum yield     absorption coefficient    

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Effect of heat transfer coefficient of steam turbine rotor on thermal stress field under off-design condition

Jie GUO,Danmei XIE,Hengliang ZHANG,Wei JIANG,Yan ZHOU

《能源前沿（英文）》 2016年 第10卷 第1期   页码 57-64 doi: 10.1007/s11708-015-0385-3

摘要： The precise calculation of temperature and thermal stress field of steam turbine rotor under off-design conditions is of paramount significance for safe and economic operation, in which an accurate calculation of heat transfer (HT) coefficient plays a decisive role. HT coefficient changes dramatically along with working conditions. First, a finite element analysis of rotor model, applied with ordinary rotor materials, has been conducted to investigate the temperature and thermal stress difference along with the change of HT coefficient from 20 W/(m ·°C) to 20000 W/(m ·°C). Next, the differentiation between existing empirical formulas has been analyzed from the aspect of physical significance of non-dimension parameters. Finally, a verifying case of the cold startup of a 1000MW unit has been proceeded. The result shows that the accuracy of coefficient calculation when steam parameters are low has a greater influence on that of rotor temperature and thermal stress, which means a precise empirical HT coefficient formula, like the Sarkar formula is strongly recommended. When steam parameters are high and HT coefficient is larger than 10 W/(m ·°C), there will be barely any influence on the calculation of thermal stress. This research plays a constructive role in the calculation and analysis of thermal stress.

关键词： steam turbine     rotor     thermal stress     heat transfer coefficient     empirical formula    

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《联合国气候变化框架公约》第26次缔约方大会召开

Sean O'Neill

《工程（英文）》 2022年 第11卷 第4期   页码 6-8 doi: 10.1016/j.eng.2022.02.004

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Dimensionality reduction and prediction of soil consolidation coefficient using random forest coupling

Hai-Bang LY; Huong-Lan Thi VU; Lanh Si HO; Binh Thai PHAM

《结构与土木工程前沿（英文）》 2022年 第16卷 第2期   页码 224-238 doi: 10.1007/s11709-022-0812-6

摘要： The consolidation coefficient of soil (Cv) is a crucial parameter used for the design of structures leaned on soft soi. In general, the Cv is determined experimentally in the laboratory. However, the experimental tests are time-consuming as well as expensive. Therefore, researchers tried several ways to determine Cv via other simple soil parameters. In this study, we developed a hybrid model of Random Forest coupling with a Relief algorithm (RF-RL) to predict the Cv of soil. To conduct this study, a database of soil parameters collected from a case study region in Vietnam was used for modeling. The performance of the proposed models was assessed via statistical indicators, namely Coefficient of determination (R2), Root Mean Squared Error (RMSE), and Mean Absolute Error (MAE). The proposal models were constructed with four sets of soil variables, including 6, 7, 8, and 13 inputs. The results revealed that all models performed well with a high performance (R2 > 0.980). Although the RF-RL model with 13 variables has the highest prediction accuracy ( R2 = 0.9869), the difference compared with other models was negligible (i.e., R2 = 0.9824, 0.9850, 0.9825 for the cases with 6, 7, 8 inputs, respectively). Thus, it can be concluded that the hybrid model of RF-RL can be employed to predict Cv based on the basic soil parameters.

关键词： soil consolidation coefficient     machine learning     random forest     Relief    

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标题 作者 时间 类型 操作

Comprehensive performance analysis and optimization of 1,3-dimethylimidazolylium dimethylphosphate-water

Gorakshnath TAKALKAR, Ahmad K. SLEITI

期刊论文

Performance of rolling piston type rotary compressor using fullerenes (C70) and NiFe

Ruixiang WANG,Yihao ZHANG,Yi LIAO

期刊论文

How diplomacy saved the COP21 Paris Climate Conference, but now, can we save ourselves?

D. Nathaniel MULCAHY, David L. MULCAHY

期刊论文

Nonlinear design-point performance adaptation approaches and their comparisons for gas turbine applications

Y. G. LI, P. PILIDIS,

期刊论文

>In situ growth of phosphorized ZIF-67-derived amorphous CoP/Cu2O@CF electrocatalyst

期刊论文

Evaluation of the performance of a centralized ground-water heat pump system in cold climate region

Shilei LU,Zhe CAI,Li ZHANG,Yiran LI

期刊论文

建设项目协调管理绩效评价

郭峰,刘慧

期刊论文

Experimental study on performance of passive and active solar stills in Indian coastal climatic condition

R. LALITHA NARAYANA, V. RAMACHANDRA RAJU

期刊论文

RETRACTED ARTICLE: Momentum exchange coefficient for two jet flows mixing in a tee junction

期刊论文

原子界面催化合成SnP/CoP异质纳米晶嵌入碳杂化物用于高功率型锂离子电池

胡晨, 胡彦杰, 陈爱平, 段学志, 江浩, 李春忠

期刊论文

Experimental study of heat transfer coefficient with rectangular baffle fin of solar air heater

Foued CHABANE,Nesrine HATRAF,Noureddine MOUMMI

期刊论文

A photolysis coefficient for characterizing the response of aqueous constituents to photolysis

David R. HOKANSON,Ke LI,R. Rhodes TRUSSELL

期刊论文

Effect of heat transfer coefficient of steam turbine rotor on thermal stress field under off-design condition

Jie GUO,Danmei XIE,Hengliang ZHANG,Wei JIANG,Yan ZHOU

期刊论文

《联合国气候变化框架公约》第26次缔约方大会召开

Sean O'Neill

期刊论文

Dimensionality reduction and prediction of soil consolidation coefficient using random forest coupling

Hai-Bang LY; Huong-Lan Thi VU; Lanh Si HO; Binh Thai PHAM

期刊论文